Lithium-ion Batteries Explained

LIBCOIN Cylindrical LIB Cell's

Most batteries cells contain three basic parts: electrodes (cathode & anode) , an electrolyte and a separator.

There are two electrodes in every battery. Both are made of conductive materials, but they serve different roles. One electrode, known as the cathode, connects to the positive end of the battery and is where the electrical current leaves (or electrons enter) the battery during discharge, which is when the battery is being used to power something. The other electrode, known as the anode, connects to the negative end of the battery and is where the electrical current enters (or electrons leave) the battery during discharge. 

Between these electrodes, as well as inside them, is the electrolyte. This is a liquid or gel-like substance that contains electrically charged particles, or ions. The ions combine with the materials that make up the electrodes, producing chemical reactions that allow a battery to generate an electric current.

The final part of the battery, the separator, is fairly straightforward. The separator's role is to keep the anode and the cathode separated from each other inside the battery. Without a separator, the two electrodes would come into contact, which would create a short circuit and prevent the battery from working properly

Battery Basics

Although all batteries work in more or less the same way, different kinds of batteries do have different features. Here are a few terms that come up often in any discussion of batteries:

Voltage: When it comes to batteries, voltage — also known as nominal cell voltage — describes the amount of electrical force, or pressure, at which free electrons move from the positive end of the battery to the negative end. In lower-voltage batteries, a current moves more slowly (with less electrical force) out of the battery than in a battery with a higher voltage (more electrical force). The batteries in a flashlight typically have a voltage of 1.5 volts. However, if a flashlight uses two batteries in a series, these batteries, or cells, have a combined voltage of 3 volts.

Lead-acid batteries, like the ones used in most nonelectric cars, usually have a voltage of 2.0 volts. But there are usually six of these cells connected in series in a car battery, which is why you've likely heard such batteries referred to as 12-volt batteries.

Lithium-cobalt-oxide batteries — the most common type of Li-ion battery found in consumer electronics — have a nominal voltage of about 3.7 volts.

Amps: An amp, or ampere, is a measure of electrical current, or the number of electrons that are flowing through a circuit within a particular time frame.

Capacity: Capacity, or cell capacity, is measured in ampere-hours, which is the number of hours the battery can supply a particular amount of electrical current before its voltage drops below a certain threshold.  EG- A 9-volt alkaline battery — the kind used in portable radios — is rated at 1 ampere-hour, which means this battery can continuously supply one ampere of current for 1 hour before it reaches the voltage threshold and is considered depleted.

Power density: Power density describes the amount of power a battery can deliver per unit weight often expressed as (Wh/kg). For electric vehicles, power density is important because it tells you how fast the car can accelerate from 0 to 60 mph (97 km/h). Engineers are constantly trying to come up with ways to make batteries smaller without diminishing their power density.

Energy density: Energy density describes how much energy a battery is capable of delivering, divided by the battery's volume or mass, and often expressed as (Wh/L). This number corresponds to things that have a big impact on users, such as how long you can use your cellphone before recharging or how far you can drive your electric car before stopping to recharge it.

How a battery works

To envision how a battery works, picture yourself putting alkaline batteries, like double AAs, into a flashlight. When you put those batteries into the flashlight and then turn it on, what you're really doing is completing a circuit. The stored chemical energy in the battery converts to electrical energy, which travels out of the battery and into the base of the flashlight's bulb, causing it to light up. Then, the electric current re-enters the battery, but at the opposite end from where it came out originally.

All of the parts of the battery work together to make the flashlight light up. The electrodes in the battery contain atoms of certain conducting materials. For instance, in an alkaline battery, the anode is typically made of zinc, and manganese dioxide acts as the cathode. And the electrolyte between and inside those electrodes contains ions. When these ions meet up with the electrodes' atoms, certain electrochemical reactions take place between the ions and the electrodes' atoms.

The series of chemical reactions that occurs in the electrodes are collectively known as oxidation-reduction (redox) reactions. In a battery, the cathode is known as the oxidizing agent because it accepts electrons from the anode. The anode is known as the reducing agent, because it loses electrons. Ultimately, these reactions result in the flow of ions between the anode and the cathode, as well as the freeing of electrons from the atoms of the electrode.

These free electrons congregate inside the anode (the bottom, flat part of an alkaline battery). As a result, the two electrodes have different charges: The anode becomes negatively charged as electrons are released, and the cathode becomes positively charged as electrons (which are negatively charged) are consumed. This difference in charge causes the electrons to want to move toward the positively charged cathode. However, they don't have a way to get there inside the battery because the separator prevents them from doing so.

When you flick the switch on your flashlight, all that changes. The electrons now have a path to get to the cathode. But first, they have to pass through the base of your flashlight's bulb. The circuit is completed when the electric current re-enters the battery through the top of the battery at the cathode.

 

Rechargeable vs. non-rechargeable

For primary batteries, like those in a flashlight, the reactions that fuel the battery will eventually stop happening, which means that the electrons that provide the battery with its charge will no longer create an electrical current. When this happens, the battery is discharged or dead.

You have to throw such batteries away, because the electrochemical processes that made the battery produce energy cannot be reversed. However, the electrochemical processes that occur’s within secondary, or rechargeable, batteries can be reversed by providing electrical energy to the battery. For example, this happens when you plug your cellphone battery into a charger connected to a power source.

The most common secondary batteries in use today are lithium-ion (Li-ion) batteries, which power most consumer electronic devices. These batteries typically contain a carbon anode, a cathode made of lithium cobalt dioxide and an electrolyte containing a lithium salt in an organic solvent. Other rechargeable batteries include nickel-cadmium (NiCd) and nickel-metal hydride (NiMH) batteries, which can be used in things like electric vehicles and cordless power tools. Lead-acid (Pb-acid) batteries are commonly used to power cars and other vehicles for starting, lighting and ignition.

All of these rechargeable batteries operate under the same principle. When you plug the battery into a power source, the flow of electrons changes direction, and the anode and the cathode are returned to their original states.

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